Insight into tribological and corrosion behaviour of binderless TiCxNy ceramic composites processed via pulsed electric current sintering technique

The study presents the corrosion behaviour and wear response of pulsed electric current sintered binderless TiC₅₀N₅₀, TiC₇₀N₃₀, and TiC₉₀N₁₀ based ceramic composites, consolidated by spark plasma sintering (SPS), and the relative densities were evaluated using the Archimedes principle. The microstructural evolutions of the sintered samples were examined through various microscopy techniques, and their susceptibility to corrosion in aggressive chloride environment was assessed using open circuit potential, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. The microstructural examination of the specimens showed the presence of different phases within the titanium carbonitride (TiCN) cermets. The wear resistance evaluated using the frictional coefficient (COF) and calculated wear rate showed that the specimens exhibited an improved resistance. The specimens further showed enhanced resistance to corrosion in the test electrolyte, as the TiC₅₀N₅₀ cermet displayed enhanced resistance to the aggressive chloride ions in comparison to the other specimens.     

Designing amorphous formulations of polyphenols with naringin by spray-drying for enhanced solubility and permeability

Naringin (NAR), a major flavanone (FVA) glycoside, is a component of food mainly obtained from grapefruit. We used NAR as a food additive to improve the solubility and permeability of hydrophobic polyphenols used as supplements in the food industry. The spray-dried particles (SDPs) of NAR alone show an amorphous state with a glass transition temperature (T_g) at 93.2 °C. SDPs of hydrophobic polyphenols, such as flavone (FVO), quercetin (QCT), naringenin (NRG), and resveratrol (RVT) were prepared by adding varying amounts of NAR. All SDPs of hydrophobic polyphenols with added NAR were in an amorphous state with a single T_g, but SDPs of hydrophobic polyphenols without added NAR showed diffraction peaks derived from each crystal. The SDPs with NAR could keep an amorphous state after storage at a high humidity condition for one month, except for SDPs of RVT/NAR. SDPs with NAR enhanced the solubility of hydrophobic polyphenols, especially NRG solubility, which was enhanced more than 9 times compared to NRG crystal. The enhanced solubility resulted in the increased membrane permeability of NRG. The antioxidant effect of the hydrophobic NRG was also enhanced by the synergetic effect of NAR. The findings demonstrated that NAR could be used as a food additive to enhance the solubility and membrane permeability of hydrophobic polyphenols.     

各种粒度表征技术的相关性研究

对几种普遍使用的粒度测试技术进行了比较,认为激光衍射法测量结果的重复性最好,测量精度高,对粒径范围较窄的球形粉体(单分散颗粒),分别采用激光衍射法、电阻法、沉降法和显微镜法测量的中位径(D50)值具有可比性;对粒径范围较宽的球形粉体,只有激光衍射法、电阻法和显微镜法测量的中位径D50值具有可比性,沉降法的测量结果相对误...     

电子束重熔Ni60A自熔合金涂层的研究

用电子束重熔、等离子喷涂和等离子堆焊方法制备Ni60A自熔合金涂层。通过SEM、电子能谱和显微硬度分析表明,电子束重熔涂层与基体的结合较好、气孔率较低、细小的脆性相在涂层中起弥散强化作用,其显微硬度最高。磨损实验也证明了电子束重熔涂层的耐磨性最好。     

水煤浆粒度测试技术的比较研究

粒度级配技术是水煤浆制浆技术的关键，快速准确地测量水煤浆中煤粒的粒度分布是实现这一技术的基础；目前最为流行的测量方法是激光粒度仪，其理论依据主要有Fraunhofer衍射理论和Mie散射理论；论文通过试验比较，系统研究了各种常用测量方法的特点。     

新疆尉犁蛭石矿中金云母/蛭石混层结构研究

蛭石矿中常伴生有金/黑云母结构,云母层的存在严重影响了蛭石矿的性能,现有方法不能充分揭示混层的晶体结构特征和蛭石晶层及金云母晶层含量。本文以新疆尉犁蛭石矿为研究对象,利用X-射线衍射(XRD)和X射线荧光光谱(XRF)研究尉犁蛭石结构和相含量。以XRD强度理论和分子量为基础,建立新型水金云母(金云母-蛭石的1∶1规则间层矿物)的参比强度近似计算方法,研究水金云母分子量变化对于定量相分析结果的影响,并与已有的分晶层方法计算得到的各晶层含量进行系统比较。结果表明新疆尉犁蛭石由24.56%的蛭石和75.44%的水金云母组成;以参比强度为基础的XRD定量分析方法具有结果可靠、分析简单,同时可以获得层状硅酸盐多层次结构信息的优点。     

茂名山阁高岭石晶体结构有序度研究

本文应用X射线衍射对茂名山阁高岭石晶体结构有序度进行了深入研究,作者提出应用嵌晶的厚度与宽度比值来判断高岭石结构有序度高低。研究结果表明,茂名山阁高岭石属典型的高有序度1T型高岭石,为国内少见。其衍射谱线分解非常清晰,(001)和(002)衍射线角宽度值0.20—0.32,结晶度指数1.29—1.47,(001)结晶方向有序序列晶胞数40—54个,嵌晶的厚度与宽度比值为0.70—0.98。随着高岭石埋深增大,其结构有序度呈下降趋势。     

Ni(Zr)Si薄膜热稳定性及其肖特基势垒二极管的电学特性

提出在Ni中掺入夹层Zr的方法来提高NiSi的热稳定性．具有此结构的薄膜,600～800℃快速热退火后,薄层电阻保持较低值,小于2Ω/□．经XRD和Raman光谱分析表明,薄膜中只存在低阻NiSi相,而没有高阻NiSi2相生成．Ni(Zr)Si的薄层电阻由低阻转变为高阻的温度在800℃以上,比没有掺Zr的镍硅化物的转变温度上限提高了100℃．Ni(Zr)Si/Si肖特基势垒二极管能够经受650～800℃不同温度的快速热退火,肖特基接触特性良好,肖特基势垒高度为0.63eV,理想因子接近于1．     

洪水淹没区上风向抗洪建筑群体布置对其下风向建筑上波浪荷载的影响

介绍了易遭受洪灾的城市（镇）永恒选型原则，对半透空式结构房屋消浪作用的原理进行了分析，并从波浪作用的特点入手，提出了半透空式抗洪建筑成群体布置时削减波浪作用的实用计算方法，以供洪水机遇较高的城市（镇）规划建设参考。     

黄土构造节理型地裂缝的地球物理勘探

采用地球物理勘探中的地震绕射波方法、高密度电法和地质雷达3种方法对黄土构造节理型地裂缝进行了探测尝试。结果表明,这些手段对探测黄土构造节理型地裂缝是有效的,地震绕射波方法可给出地裂缝的位置、深度等参数;高密度电法方法不仅可以给出其位置,还可得到其宽度参数;而地质雷达的探测结果可给出近地表数m内地裂缝(盲沟)的高精度图像,更适合探测隐伏地裂缝。